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Assessment of a Metallurgical Plant Impact on the Sea of Azov
Corresponding Author(s) : Elena Neverova-Dziopak
Geomatics and Environmental Engineering,
Vol. 16 No. 4 (2022): Geomatics and Environmental Engineering
Abstract
Ferrous metallurgy enterprises have a negative impact on the air, soil, and water environment. The activities of metallurgy enterprises include a wide range of production processes (from the extraction of metals from ores to obtaining finished products) and is associated with the formation of a large amount of waste. Industrial wastewater discharge is the main source of aquatic area pollution. An assessment of the impact of wastewater discharged from the Azovstal Iron & Steel Works metallurgical plant on the state of the coastal waters of the Sea of Azov near Mariupol (Ukraine) is presented in the article. The assessment was carried out in accordance with the current Ukrainian legislation and the adopted methodology for water state assessment. The assessment was based on the available monitoring data of sea water in the area of wastewater discharges in the period 2016–2020. The assessment was carried out using the aggregated numerical indices, as well as taking into account the “limiting criterion principle”. Such a methodological approach allowed for a comprehensive assessment of the sea water quality class as well as its sanitary and ecological condition. The results of the assessment allowed us to ascertain the negative impact of industrial wastewater from the metallurgical plant on the coastal zone of the Azov Sea, which made it unsuitable for communal and recreational purposes.
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- Qadri R., Faiq M.A.: Freshwater pollution: effects on aquatic life and human health. [in:] Qadri H., Bhat R.A., Mehmood M.A., Dar G.H. (eds.), Fresh Water Pollution Dynamics and Remediation, Springer, Singapore 2020, pp. 15–26. https://doi.org/10.1007/978-981-13-8277-2_2.
- Hossain M., Patra P.K.: Water pollution index – A new integrated approach to rank water quality. Ecological Indicators, vol. 117, 2020, 106668. https://doi.org/10.1016/j.ecolind.2020.106668.
- Posthuma L., Zijp M.C., De Zwart D., Van de Meent D., Globevnik L., Koprivsek M., Focks A. et al.: Chemical pollution imposes limitations to the ecological status of European surface waters. Scientific Reports, vol. 10, 2020, pp. 1–12. https://doi.org/10.1038/s41598-020-71537-2.
- Steffen W., Richardson K., Rockström J., Cornell S.E., Fetzer I., Bennett E.M., Biggs R. et al.: Planetary boundaries: Guiding human development on a changing planet. Science, vol. 347, no. 6223, 2015, 1259855. https://doi.org/10.1126/science.1259855.
- Davis M.L., Cornwell D.A.: Introduction to Environmental Engineering: 5th Edition. McGraw-Hill, New York 2013.
- Fetke R., Carpa R., Drăgan-Bularda M.: Forms of water pollution – short review. Studii și cercetări, Biology, vol. 19, 2014, pp. 99–110.
- Malik K.: Human development report 2014: Sustaining human progress: Reducing vulnerabilities and building resilience. United Nations Development Programme, New York 2014.
- Rybicka E.H.: Impact of mining and metallurgical industries on the environment in Poland. Applied Geochemistry, vol. 11, 1996, pp. 3–9. https://doi.org/10.1016/0883-2927(95)00083-6.
- Luo J., Feng X., Han H., Wang N.: Identification for discharged characteristics of fine particulate matter from coke chemical industry in northern China. International Journal of Environmental Science and Technology, vol. 110, 2022, pp. 1–10. https://doi.org/10.1007/s13762-022-04114-x.
- Yilmaz C., Wendelstorf J., Turek T.: Modeling and simulation of hydrogen injection into a blast furnace to reduce carbon dioxide emissions. Journal of Cleaner Production, vol. 154, 2017, pp. 488–501. https://doi.org/10.1016/j.jclepro.2017.03.162.
- Denisov D., Terentjev P., Valkova S., Kudryavtzeva L.: Small lakes ecosystems under the impact of non-ferrous metallurgy (Russia, Murmansk Region). Environment, vol. 7, 2020, 29. https://doi.org/10.3390/environments7040029.
- Glushakova O.V., Chernikova O.P.: Influence of Ferrous Metallurgy Enterprises on Atmospheric Air Quality as an Environmental Component of Sustainable Development of Territories. Report 1. Steel in Translation, vol. 51, 2021, pp. 249–256. https://doi.org/10.3103/S0967091221040057.
- Zolotova E.: Studies of Soils and Vegetation on Non-ferrous Metallurgy Slag Dumps. International Journal of Bioresource and Stress Management, vol. 12, 2021, pp. 40–46. https://doi.org/10.23910/1.2021.2178a.
- Doležalová Weissmannová H., Mihočová S., Chovanec P., Pavlovský J.: Potential ecological risk and human health risk assessment of heavy metal pollution in industrial affected soils by coal mining and metallurgy in Ostrava, Czech Republic. International Journal of Environmental Research and Public Health, vol. 16, 2019, 4495. https://doi.org/10.3390/ijerph16224495.
- Iluţiu-Varvara D.A.: Researching the Hazardous Potential of Metallurgical Solid Wastes. Polish Journal of Environmental Studies, vol. 25, 2016, pp. 147–152. https://doi.org/10.15244/pjoes/60178.
- Nosova O.V., Karmanovskaya N.V., Galishevskaya V.V.: The study of water flows of technological water cycle and wastewater of metallurgical production concerning pollution content. Periódico Tchê Química, vol. 15, 2018, pp. 550–555. https://doi.org/10.52571/PTQ.v15.n30.2018.554_Periodico30_pgs_550_555.pdf [access: 17.05.2022].
- Berestovoi A., Khliestova O., Zinchenko S., Berestovoi I.: Osnovy algoritma vybora varianta transporta zatverdevayushchikh zhidkostey promyshlenno-agrarnogo kompleksa pri nalichii morskikh perevozok [Oсновы алгоритма выбора варианта транспорта затвердевающих жидкостей промышленно-аграрного комплекса при наличии морских перевозок – Bases of the algorithm for selecting a transport option of harding liquids of the industrial-agricultural complex in the presence of sea transportation]. Journal of Mechanical Engineering and Transport, vol. 2, 2020, pp. 4–10. https://doi.org/10.31649/2413-4503-2020-12-2-4-10.
- Neverova-Dziopak E., Dan O.: Klasyfikacja stanu przybrzeżnych wód morskich na Ukrainie na przykładzie Morza Azowskiego w rejonie Mariupola. Ochrona Środowiska, vol. 40, 2018, pp. 29–34.
- Rodionov A., Danilina M., Buslaev S.: Improving the sustainability of metal-producing industries in Russia. IOP Conference Series: Materials Science and Engineering, vol. 1001, 2020, 012036. https://doi.org/10.1088/1757-899X/1001/1/012036.
- Leal Filho W., Butorina I.: Approaches to Handling Environmental Problems in Mining and Metallurgical Regions. Management of Environmental Quality, vol. 15, 2004, 79. https://doi.org/10.1108/meq.2004.15.1.79.1.
- World Steel Association: World Steel in Figures 2022 now available. Dated on 7.06.2022. https://worldsteel.org/media-centre/press-releases/2022/world-steel-in-figures-2022-now-available/ [access: 21.06.2022].
- World steel in figures. World Steel Association, Brussels 2022.
- World steel in figures. World Steel Association, Brussels 2021.
- World steel in figures. World Steel Association, Brussels 2020.
- World steel in figures. World Steel Association, Brussels 2019.
- World steel in figures. World Steel Association, Brussels 2018.
- World steel in figures. World Steel Association, Brussels 2017.
- World steel in figures. World Steel Association, Brussels 2016.
- World steel in figures. World Steel Association, Brussels 2015.
- World steel in figures. World Steel Association, Brussels 2014.
- World steel in figures. World Steel Association, Brussels 2013.
- World steel in figures. World Steel Association, Brussels 2012.
- Stalinsky D.V., Mantula V.D., Epstein S.I., Muzykina Z.S., Kondratenko A.I.: Analiz vodopotrebleniya i vodootvedeniya na predpriyatiyakh gorno-metallurgicheskogo kompleksa Ukrainy [Анализ водопотребления и водоотведения на предприятиях горно-металлургического комплекса Украины]. Ekologiya i promyshlennost’ [Экология и промышленность], no. 4, 2007, pp. 15–20.
- Matukhno E., Belokon K., Shatokha V., Baranova T.: Ecological aspects of sustainable development of metallurgical complex in Ukraine. Procedia Environmental Science, Engineering and Management, vol. 6, 2019, pp. 671–680.
- State Statistics Service of Ukraine. http://www.ukrstat.gov.ua [access: 23.10.2021].
- Ukraine 3D map. https://sketchfab.com/3d-models/ukraine-3d-map-77a62b26e37246f5b5f10228b6e9ef3e [access: 23.10.2021].
- Europe-Ukraine (orthographic projection; disputed territory). https://din.wikipedia.org/wiki/Apamdu%C3%B6%C3%B6t:Europe-Ukraine_(orthographic_projection;_disputed_territory).svg [access: 23.10.2021].
- V zonu khimicheskogo zarazheniya pri avarii na MK «Azovstal’» popadut 200 tysyach chelovek – MChS [В зону химического заражения при аварии на МК «Азовсталь» попадут 200 тысяч человек – МЧС]. Dated on 1.06.2017. https://www.smdnr.ru/v-zonu-himicheskogo-zarazheniya-pri-avarii-na-mk-azovstal-popadut-200-000-chelovek-mchs [access: 23.10.2021].
- Dan O., Neverova-Dziopak E., Butenko E., Kapustin A.: Analysis of Mariupol metallurgical enterprises influence on ecological state of surface waters. Geomatics and Environmental Engineering, vol. 11, 2017, pp. 25–31. https://doi.org/10.7494/geom.2017.11.1.25.
- Kosarev A.N., Kostianoy A.G., Shiganova T.A.: The Sea of Azov. [in:] Kostianoy A.G., Kosarev A.N. (eds.), The Black Sea Environment, The Handbook of Environmental Chemistry, vol. 5Q, Springer, Berlin, Heidelberg 2007, pp. 63–89. https://doi.org/10.1007/698_5_091.
- Kosyan R.D., Krylenko M.V.: Modern state and dynamics of the Sea of Azov coasts. Estuarine, Coastal and Shelf Science, vol. 224, 2019, pp. 314–323. https://doi.org/10.1016/j.ecss.2019.05.008.
- The Editors of Encyclopaedia Britannica: Sea of Azov. Encyclopedia Britannica. Dated on 8.07.2009. https://www.britannica.com/place/Sea-of-Azov [access: 19.09.2021].
- Dashkevich L.V., Berdnikov S.V., Kulygin V.V.: Many-year variations of the average salinity of the Sea of Azov. Water Resources, vol. 44, 2017, pp. 749–757. https://doi.org/10.1134/S0097807817040042.
- Dashkevich L.V., Berdnikov S.V.: Climatic changes and salinity of the Sea of Azov for 100 years. International Multidisciplinary Scientific GeoConference: SGEM, vol. 2, 2016, pp. 719–726.
- Plyaka P., Glushchenko G., Gerasyuk V., Kleshchenkov A., Grigorenko K., Shevchenko M., Yurasov Y., Valov G., Tron I., Popovyan G., Berdnikov S.: Investigation on the Chlorophyll-a Content of Phytoplankton in the Sea of Azov and the Don River by the Fluorescence Method. [in:] Grigoryeva N. (ed.), Fluorescence Methods for Investigation of Living Cells and Microorganisms, IntechOpen, London 2020, pp. 139–149. https://doi.org/10.5772/intechopen.83296.
- Dan O.: Sulfides removal from slag infiltrate with layered double hydroxides. Desalination and Water Treatment, vol. 232, 2021, pp. 339–345. https://doi.org/10.5004/dwt.2021.27522.
- Poletaieva H., Fediushko M., Shevchenko S.: Pollutants of the Sea of Azov. 2017. http://eztuir.ztu.edu.ua/bitstream/handle/123456789/6446/75.pdf?sequence=1&isAllowed=y [access: 19.09.2021].
- Khavanskiy A.D., Latun V.V., Khoroshev O.A., Merinova Y.Y., Bogachev I.V., Kravchenko A.M., Konovalov A.N.: Ecological and Economic Assessment and Dangerous Coastal Processes in the Coastal Zone of the Azov Sea. Atlantis Highlights in Material Sciences and Technology, vol. 1, 2019, pp. 597–602. https://doi.org/10.2991/isees-19.2019.118.
- Preisner M., Neverova-Dziopak E., Kowalewski Z.: An analytical review of different approaches to wastewater discharge standards with particular emphasis on nutrients. Environmental Management, vol. 66, 2020, pp. 694–708. https://doi.org/10.1007/s00267-020-01344-y.
- Gavrilenko O.P.: Ekogeografіya Ukrainy [Екогеографія України]. Znannia, Kyiv 2008.
- Vodnyy kodeks Ukrainy [Водний кодекс України]. Adopted by the Verkhovna Rada of Ukraine on the 6th of June 1995 № 213/95-ВР. Natsionalniy knizhkoviy proekt, Kyiv 2013.
- Verkhovna Rada of Ukraine: Pro okhoronu navkolishnogo prirodnogo seredovishcha [Про охорону навколишнього природного середовища]. Law of Ukraine dated on the 21st of June 1991 № 1268-XII. Vidomosti Verhvonoyi Radi Ukrayini, 41 (1991) 546.
- State Committee for Construction, Architecture and Housing Policy of Ukraine: Pravila priymannya stіchnikh vod pіdpriєmstv u komunalnі ta vіdomchі sistemi kanalіzatsії naselenikh punktіv Ukrainy [Правила приймання стічних вод підприємств у комунальні та відомчі системи каналізації населених пунктів України]. Dated on 26.04.2002.
- Lozanskyi V.R.: Problema kompleksnykh otsenok kachestva poverkhnostnykh vod i puti eye resheniya [Проблема комплексных оценок качества поверхностных вод и пути ее решения]. [in:] Kompleksnyye otsenki kachestva poverkhnostnykh vod [Комплексные оценки качества поверхностных вод]. Gidrometeoizdat, Leningrad 1984, pp. 6–14.
- Government of Ukraine: Pro zatverdzhennya Pravil okhoroni vnutrіshnіkh morskikh vod і teritorіalnogo morya vіd zabrudnennya ta zasmіchennya [Про затвердження Правил охорони внутрішніх морських вод і територіального моря від забруднення та засмічення]. Kyiv 1996.
- Hydrochemical Institute of the Federal Service of Russia for Hydrometeorology and Environmental Monitoring: Metod kompleksnoy otsenki stepeni zagryazneniya poverkhnostnykh vod po gidrokhimicheskim pokazatelyam [Метод комплексной оценки степени загрязнения поверхностных вод по гидрохимическим показателям]. 2004.
- Shitikov V.K., Rozenberg G.S., Zinchenko T.D.: Kolichestvennaya gidroekologiya: metody. kriterii. resheniya. Kniga 1 [Количественная гидроэкология: методы, критерии, решения. Книга 1]. Nauka, Moskva 2005.
- Habarova E.I., Rodzin I.A., Nikitina S.V., Leontieva S.V.: Raschet i otsenka ekologo-znachimykh parametrov [Расчет и оценка эколого-значимых параметров]. MITKhT, Moskva 2010.
- Milanović A., Milijašević D., Brankov J.: Assessment of polluting effects and surface water quality using water pollution index: a case study of Hydro-system Danube-Tisa-Danube, Serbia. Carpathian Journal of Earth and Environmental Sciences, vol. 6, 2011, pp. 269–277.
- SanPiN 4630-88: Sanіtarnі pravila і normi okhoroni poverkhnevikh vod vіd zabrudnennya [Санітарні правила і норми охорони поверхневих вод від забруднення]. 1991.
- SanPiN 2.1.5.980-00: Gigiyenicheskiye trebovaniya k okhrane poverkhnostnykh vod [Гигиенические требования к охране поверхностных вод]. 2000.
- Federal Service for Hydrometeorology and Environmental Monitoring of USSR: Vremennyye metodicheskiye ukazaniya po kompleksnoy otsenke kachestva poverkhnostnykh i morskikh vod po gidrokhimicheskim pokazatelyam [Временные методические указания по комплексной оценке качества поверхностных и морских вод по гидрохимическим показателям]. Moskva 1986.
- GOST 27065-86: Kachestvo vody. Ponyatiya i opredeleniyam [Качество воды. Понятия и определения]. Ministry of Land Reclamation and Water Management of the USSR, 1987.
- Glotova N.V.: Monitoring okruzhayushchey sredy [Мониторинг окружающей среды]. Izdatelstvo Chelyabinsk, Chelyabinsk 2006.
- Gagarina O.V.: Otsenka i normirovaniye kachestva prirodnykh vod: kriterii. metody. sushchestvuyushchiye problemy [Оценка и нормирование качества природных вод: критерии, методы, существующие проблемы]. Izdatel’stvo «Udmurtskiy universitet», Izhevsk 2012.
- Rozporządzenie Ministra Infrastruktury z dnia 25 czerwca 2021 r. w sprawie klasyfikacji stanu ekologicznego, potencjału ekologicznego i stanu chemicznego oraz sposobu klasyfikacji stanu jednolitych części wód powierzchniowych, a także środowiskowych norm jakości dla substancji priorytetowych. Dz.U. 2021 poz. 1475.
- Khabarova E.I., Rozdin I.A., Nikitina S.V., Leont’eva S.V.: Raschet i otsenka ekologo-znachimykh parametrov [Расчет и оценка эколого-значимых параметров]. MITKhT, Moskva 2010.
- Horton R.K.: An index number system for rating water quality. Journal of the Water Pollution Control Federation, vol. 37, 1965, pp. 300–306.
- Kachroud M., Trolard F., Kefi M., Jebari S., Bourrié G.: Water quality indices: Challenges and application limits in the literature. Water, vol. 11, 2019, 361. https://doi.org/10.3390/w11020361.
- Barasheva S.V., Karataev O.R.: Tendentsii zagryazneniya okruzhayushchey sredy stochnymi vodami razlichnykh promyshlennykh predpriyatiy [Тенденции загрязнения окружающей среды сточными водами различных промышленных предприятий]. Koncept, vol. 20, 2014, pp. 1681–1685.
- Kapustin A.E.: Zagryazneniye vod Azovskogo morya – problemy i resheniya [Загрязнение вод Азовского моря – проблемы и решения]. Water for Mariupol: materials of the round table “Problems of providing Mariupol with quality water and possible ways to solve them”, vol. 1, 2016, pp. 15–19.
References
Qadri R., Faiq M.A.: Freshwater pollution: effects on aquatic life and human health. [in:] Qadri H., Bhat R.A., Mehmood M.A., Dar G.H. (eds.), Fresh Water Pollution Dynamics and Remediation, Springer, Singapore 2020, pp. 15–26. https://doi.org/10.1007/978-981-13-8277-2_2.
Hossain M., Patra P.K.: Water pollution index – A new integrated approach to rank water quality. Ecological Indicators, vol. 117, 2020, 106668. https://doi.org/10.1016/j.ecolind.2020.106668.
Posthuma L., Zijp M.C., De Zwart D., Van de Meent D., Globevnik L., Koprivsek M., Focks A. et al.: Chemical pollution imposes limitations to the ecological status of European surface waters. Scientific Reports, vol. 10, 2020, pp. 1–12. https://doi.org/10.1038/s41598-020-71537-2.
Steffen W., Richardson K., Rockström J., Cornell S.E., Fetzer I., Bennett E.M., Biggs R. et al.: Planetary boundaries: Guiding human development on a changing planet. Science, vol. 347, no. 6223, 2015, 1259855. https://doi.org/10.1126/science.1259855.
Davis M.L., Cornwell D.A.: Introduction to Environmental Engineering: 5th Edition. McGraw-Hill, New York 2013.
Fetke R., Carpa R., Drăgan-Bularda M.: Forms of water pollution – short review. Studii și cercetări, Biology, vol. 19, 2014, pp. 99–110.
Malik K.: Human development report 2014: Sustaining human progress: Reducing vulnerabilities and building resilience. United Nations Development Programme, New York 2014.
Rybicka E.H.: Impact of mining and metallurgical industries on the environment in Poland. Applied Geochemistry, vol. 11, 1996, pp. 3–9. https://doi.org/10.1016/0883-2927(95)00083-6.
Luo J., Feng X., Han H., Wang N.: Identification for discharged characteristics of fine particulate matter from coke chemical industry in northern China. International Journal of Environmental Science and Technology, vol. 110, 2022, pp. 1–10. https://doi.org/10.1007/s13762-022-04114-x.
Yilmaz C., Wendelstorf J., Turek T.: Modeling and simulation of hydrogen injection into a blast furnace to reduce carbon dioxide emissions. Journal of Cleaner Production, vol. 154, 2017, pp. 488–501. https://doi.org/10.1016/j.jclepro.2017.03.162.
Denisov D., Terentjev P., Valkova S., Kudryavtzeva L.: Small lakes ecosystems under the impact of non-ferrous metallurgy (Russia, Murmansk Region). Environment, vol. 7, 2020, 29. https://doi.org/10.3390/environments7040029.
Glushakova O.V., Chernikova O.P.: Influence of Ferrous Metallurgy Enterprises on Atmospheric Air Quality as an Environmental Component of Sustainable Development of Territories. Report 1. Steel in Translation, vol. 51, 2021, pp. 249–256. https://doi.org/10.3103/S0967091221040057.
Zolotova E.: Studies of Soils and Vegetation on Non-ferrous Metallurgy Slag Dumps. International Journal of Bioresource and Stress Management, vol. 12, 2021, pp. 40–46. https://doi.org/10.23910/1.2021.2178a.
Doležalová Weissmannová H., Mihočová S., Chovanec P., Pavlovský J.: Potential ecological risk and human health risk assessment of heavy metal pollution in industrial affected soils by coal mining and metallurgy in Ostrava, Czech Republic. International Journal of Environmental Research and Public Health, vol. 16, 2019, 4495. https://doi.org/10.3390/ijerph16224495.
Iluţiu-Varvara D.A.: Researching the Hazardous Potential of Metallurgical Solid Wastes. Polish Journal of Environmental Studies, vol. 25, 2016, pp. 147–152. https://doi.org/10.15244/pjoes/60178.
Nosova O.V., Karmanovskaya N.V., Galishevskaya V.V.: The study of water flows of technological water cycle and wastewater of metallurgical production concerning pollution content. Periódico Tchê Química, vol. 15, 2018, pp. 550–555. https://doi.org/10.52571/PTQ.v15.n30.2018.554_Periodico30_pgs_550_555.pdf [access: 17.05.2022].
Berestovoi A., Khliestova O., Zinchenko S., Berestovoi I.: Osnovy algoritma vybora varianta transporta zatverdevayushchikh zhidkostey promyshlenno-agrarnogo kompleksa pri nalichii morskikh perevozok [Oсновы алгоритма выбора варианта транспорта затвердевающих жидкостей промышленно-аграрного комплекса при наличии морских перевозок – Bases of the algorithm for selecting a transport option of harding liquids of the industrial-agricultural complex in the presence of sea transportation]. Journal of Mechanical Engineering and Transport, vol. 2, 2020, pp. 4–10. https://doi.org/10.31649/2413-4503-2020-12-2-4-10.
Neverova-Dziopak E., Dan O.: Klasyfikacja stanu przybrzeżnych wód morskich na Ukrainie na przykładzie Morza Azowskiego w rejonie Mariupola. Ochrona Środowiska, vol. 40, 2018, pp. 29–34.
Rodionov A., Danilina M., Buslaev S.: Improving the sustainability of metal-producing industries in Russia. IOP Conference Series: Materials Science and Engineering, vol. 1001, 2020, 012036. https://doi.org/10.1088/1757-899X/1001/1/012036.
Leal Filho W., Butorina I.: Approaches to Handling Environmental Problems in Mining and Metallurgical Regions. Management of Environmental Quality, vol. 15, 2004, 79. https://doi.org/10.1108/meq.2004.15.1.79.1.
World Steel Association: World Steel in Figures 2022 now available. Dated on 7.06.2022. https://worldsteel.org/media-centre/press-releases/2022/world-steel-in-figures-2022-now-available/ [access: 21.06.2022].
World steel in figures. World Steel Association, Brussels 2022.
World steel in figures. World Steel Association, Brussels 2021.
World steel in figures. World Steel Association, Brussels 2020.
World steel in figures. World Steel Association, Brussels 2019.
World steel in figures. World Steel Association, Brussels 2018.
World steel in figures. World Steel Association, Brussels 2017.
World steel in figures. World Steel Association, Brussels 2016.
World steel in figures. World Steel Association, Brussels 2015.
World steel in figures. World Steel Association, Brussels 2014.
World steel in figures. World Steel Association, Brussels 2013.
World steel in figures. World Steel Association, Brussels 2012.
Stalinsky D.V., Mantula V.D., Epstein S.I., Muzykina Z.S., Kondratenko A.I.: Analiz vodopotrebleniya i vodootvedeniya na predpriyatiyakh gorno-metallurgicheskogo kompleksa Ukrainy [Анализ водопотребления и водоотведения на предприятиях горно-металлургического комплекса Украины]. Ekologiya i promyshlennost’ [Экология и промышленность], no. 4, 2007, pp. 15–20.
Matukhno E., Belokon K., Shatokha V., Baranova T.: Ecological aspects of sustainable development of metallurgical complex in Ukraine. Procedia Environmental Science, Engineering and Management, vol. 6, 2019, pp. 671–680.
State Statistics Service of Ukraine. http://www.ukrstat.gov.ua [access: 23.10.2021].
Ukraine 3D map. https://sketchfab.com/3d-models/ukraine-3d-map-77a62b26e37246f5b5f10228b6e9ef3e [access: 23.10.2021].
Europe-Ukraine (orthographic projection; disputed territory). https://din.wikipedia.org/wiki/Apamdu%C3%B6%C3%B6t:Europe-Ukraine_(orthographic_projection;_disputed_territory).svg [access: 23.10.2021].
V zonu khimicheskogo zarazheniya pri avarii na MK «Azovstal’» popadut 200 tysyach chelovek – MChS [В зону химического заражения при аварии на МК «Азовсталь» попадут 200 тысяч человек – МЧС]. Dated on 1.06.2017. https://www.smdnr.ru/v-zonu-himicheskogo-zarazheniya-pri-avarii-na-mk-azovstal-popadut-200-000-chelovek-mchs [access: 23.10.2021].
Dan O., Neverova-Dziopak E., Butenko E., Kapustin A.: Analysis of Mariupol metallurgical enterprises influence on ecological state of surface waters. Geomatics and Environmental Engineering, vol. 11, 2017, pp. 25–31. https://doi.org/10.7494/geom.2017.11.1.25.
Kosarev A.N., Kostianoy A.G., Shiganova T.A.: The Sea of Azov. [in:] Kostianoy A.G., Kosarev A.N. (eds.), The Black Sea Environment, The Handbook of Environmental Chemistry, vol. 5Q, Springer, Berlin, Heidelberg 2007, pp. 63–89. https://doi.org/10.1007/698_5_091.
Kosyan R.D., Krylenko M.V.: Modern state and dynamics of the Sea of Azov coasts. Estuarine, Coastal and Shelf Science, vol. 224, 2019, pp. 314–323. https://doi.org/10.1016/j.ecss.2019.05.008.
The Editors of Encyclopaedia Britannica: Sea of Azov. Encyclopedia Britannica. Dated on 8.07.2009. https://www.britannica.com/place/Sea-of-Azov [access: 19.09.2021].
Dashkevich L.V., Berdnikov S.V., Kulygin V.V.: Many-year variations of the average salinity of the Sea of Azov. Water Resources, vol. 44, 2017, pp. 749–757. https://doi.org/10.1134/S0097807817040042.
Dashkevich L.V., Berdnikov S.V.: Climatic changes and salinity of the Sea of Azov for 100 years. International Multidisciplinary Scientific GeoConference: SGEM, vol. 2, 2016, pp. 719–726.
Plyaka P., Glushchenko G., Gerasyuk V., Kleshchenkov A., Grigorenko K., Shevchenko M., Yurasov Y., Valov G., Tron I., Popovyan G., Berdnikov S.: Investigation on the Chlorophyll-a Content of Phytoplankton in the Sea of Azov and the Don River by the Fluorescence Method. [in:] Grigoryeva N. (ed.), Fluorescence Methods for Investigation of Living Cells and Microorganisms, IntechOpen, London 2020, pp. 139–149. https://doi.org/10.5772/intechopen.83296.
Dan O.: Sulfides removal from slag infiltrate with layered double hydroxides. Desalination and Water Treatment, vol. 232, 2021, pp. 339–345. https://doi.org/10.5004/dwt.2021.27522.
Poletaieva H., Fediushko M., Shevchenko S.: Pollutants of the Sea of Azov. 2017. http://eztuir.ztu.edu.ua/bitstream/handle/123456789/6446/75.pdf?sequence=1&isAllowed=y [access: 19.09.2021].
Khavanskiy A.D., Latun V.V., Khoroshev O.A., Merinova Y.Y., Bogachev I.V., Kravchenko A.M., Konovalov A.N.: Ecological and Economic Assessment and Dangerous Coastal Processes in the Coastal Zone of the Azov Sea. Atlantis Highlights in Material Sciences and Technology, vol. 1, 2019, pp. 597–602. https://doi.org/10.2991/isees-19.2019.118.
Preisner M., Neverova-Dziopak E., Kowalewski Z.: An analytical review of different approaches to wastewater discharge standards with particular emphasis on nutrients. Environmental Management, vol. 66, 2020, pp. 694–708. https://doi.org/10.1007/s00267-020-01344-y.
Gavrilenko O.P.: Ekogeografіya Ukrainy [Екогеографія України]. Znannia, Kyiv 2008.
Vodnyy kodeks Ukrainy [Водний кодекс України]. Adopted by the Verkhovna Rada of Ukraine on the 6th of June 1995 № 213/95-ВР. Natsionalniy knizhkoviy proekt, Kyiv 2013.
Verkhovna Rada of Ukraine: Pro okhoronu navkolishnogo prirodnogo seredovishcha [Про охорону навколишнього природного середовища]. Law of Ukraine dated on the 21st of June 1991 № 1268-XII. Vidomosti Verhvonoyi Radi Ukrayini, 41 (1991) 546.
State Committee for Construction, Architecture and Housing Policy of Ukraine: Pravila priymannya stіchnikh vod pіdpriєmstv u komunalnі ta vіdomchі sistemi kanalіzatsії naselenikh punktіv Ukrainy [Правила приймання стічних вод підприємств у комунальні та відомчі системи каналізації населених пунктів України]. Dated on 26.04.2002.
Lozanskyi V.R.: Problema kompleksnykh otsenok kachestva poverkhnostnykh vod i puti eye resheniya [Проблема комплексных оценок качества поверхностных вод и пути ее решения]. [in:] Kompleksnyye otsenki kachestva poverkhnostnykh vod [Комплексные оценки качества поверхностных вод]. Gidrometeoizdat, Leningrad 1984, pp. 6–14.
Government of Ukraine: Pro zatverdzhennya Pravil okhoroni vnutrіshnіkh morskikh vod і teritorіalnogo morya vіd zabrudnennya ta zasmіchennya [Про затвердження Правил охорони внутрішніх морських вод і територіального моря від забруднення та засмічення]. Kyiv 1996.
Hydrochemical Institute of the Federal Service of Russia for Hydrometeorology and Environmental Monitoring: Metod kompleksnoy otsenki stepeni zagryazneniya poverkhnostnykh vod po gidrokhimicheskim pokazatelyam [Метод комплексной оценки степени загрязнения поверхностных вод по гидрохимическим показателям]. 2004.
Shitikov V.K., Rozenberg G.S., Zinchenko T.D.: Kolichestvennaya gidroekologiya: metody. kriterii. resheniya. Kniga 1 [Количественная гидроэкология: методы, критерии, решения. Книга 1]. Nauka, Moskva 2005.
Habarova E.I., Rodzin I.A., Nikitina S.V., Leontieva S.V.: Raschet i otsenka ekologo-znachimykh parametrov [Расчет и оценка эколого-значимых параметров]. MITKhT, Moskva 2010.
Milanović A., Milijašević D., Brankov J.: Assessment of polluting effects and surface water quality using water pollution index: a case study of Hydro-system Danube-Tisa-Danube, Serbia. Carpathian Journal of Earth and Environmental Sciences, vol. 6, 2011, pp. 269–277.
SanPiN 4630-88: Sanіtarnі pravila і normi okhoroni poverkhnevikh vod vіd zabrudnennya [Санітарні правила і норми охорони поверхневих вод від забруднення]. 1991.
SanPiN 2.1.5.980-00: Gigiyenicheskiye trebovaniya k okhrane poverkhnostnykh vod [Гигиенические требования к охране поверхностных вод]. 2000.
Federal Service for Hydrometeorology and Environmental Monitoring of USSR: Vremennyye metodicheskiye ukazaniya po kompleksnoy otsenke kachestva poverkhnostnykh i morskikh vod po gidrokhimicheskim pokazatelyam [Временные методические указания по комплексной оценке качества поверхностных и морских вод по гидрохимическим показателям]. Moskva 1986.
GOST 27065-86: Kachestvo vody. Ponyatiya i opredeleniyam [Качество воды. Понятия и определения]. Ministry of Land Reclamation and Water Management of the USSR, 1987.
Glotova N.V.: Monitoring okruzhayushchey sredy [Мониторинг окружающей среды]. Izdatelstvo Chelyabinsk, Chelyabinsk 2006.
Gagarina O.V.: Otsenka i normirovaniye kachestva prirodnykh vod: kriterii. metody. sushchestvuyushchiye problemy [Оценка и нормирование качества природных вод: критерии, методы, существующие проблемы]. Izdatel’stvo «Udmurtskiy universitet», Izhevsk 2012.
Rozporządzenie Ministra Infrastruktury z dnia 25 czerwca 2021 r. w sprawie klasyfikacji stanu ekologicznego, potencjału ekologicznego i stanu chemicznego oraz sposobu klasyfikacji stanu jednolitych części wód powierzchniowych, a także środowiskowych norm jakości dla substancji priorytetowych. Dz.U. 2021 poz. 1475.
Khabarova E.I., Rozdin I.A., Nikitina S.V., Leont’eva S.V.: Raschet i otsenka ekologo-znachimykh parametrov [Расчет и оценка эколого-значимых параметров]. MITKhT, Moskva 2010.
Horton R.K.: An index number system for rating water quality. Journal of the Water Pollution Control Federation, vol. 37, 1965, pp. 300–306.
Kachroud M., Trolard F., Kefi M., Jebari S., Bourrié G.: Water quality indices: Challenges and application limits in the literature. Water, vol. 11, 2019, 361. https://doi.org/10.3390/w11020361.
Barasheva S.V., Karataev O.R.: Tendentsii zagryazneniya okruzhayushchey sredy stochnymi vodami razlichnykh promyshlennykh predpriyatiy [Тенденции загрязнения окружающей среды сточными водами различных промышленных предприятий]. Koncept, vol. 20, 2014, pp. 1681–1685.
Kapustin A.E.: Zagryazneniye vod Azovskogo morya – problemy i resheniya [Загрязнение вод Азовского моря – проблемы и решения]. Water for Mariupol: materials of the round table “Problems of providing Mariupol with quality water and possible ways to solve them”, vol. 1, 2016, pp. 15–19.